XUE Qifan, LI Can, LI Jiayu, LIN Rui, WANG Jing, HU Zeyuan, HUANG Jinuo, LIU Xianghua, MO Yongyou, LUO Dongxiang, FU Nianqing
Journal of Guangzhou University(Natural Science Edition). 2026, 25(2): 49-62.
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Perovskite solar cells (PSCs) have emerged as a leading candidate for next-generation photovoltaics due to their high power conversion efficiency and low-cost processability. This review focuses on all-inorganic perovskites, providing a systematic overview of recent advances in their material properties, film morphology control, and interfacial passivation strategies. We first summarize the intrinsic advantages of all-inorganic systems in terms of thermal stability, moisture resistance, and photo-oxidation durability, while elucidating key performance-limiting factors such as surface and bulk defects, halide migration, and phase instability. We then highlight the mechanisms and effects of mainstream passivation strategies—including surface termination engineering, low-dimensional phase incorporation, and interfacial reconstruction—with representative examples such as buried interlayers, photo-switchable passivation molecules, and low-dimensional reconfiguration that enable synergistic improvements in efficiency and long-term stability. Finally, we outline future research directions: coupled multiscale in-situ characterization and theory, sustainable and dynamic molecular passivation design, lead-free and oxide-based alternatives, dimensional engineering of quasi-2D structures, and scalable fabrication with standardized stability evaluation protocols. This review aims to provide a comprehensive perspective and roadmap for the material innovation and device engineering of all-inorganic perovskite photovoltaics.