ZHANG Chao-sheng, CAO Long, CHEN Qiu-li
. 2017, 16(6): 69-76.
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In order to improve the performance of environmental hormone in the treatment of phthalic acid esters (PAEs), the removal efficiency and degradation mechanism of PAEs (DMP, DEP, DBP, DEHP) by ozone, activated carbon, ultrafiltration and two kinds of combined processes were studied in this paper. The results showed that the single ozone oxidation, activated carbon adsorption, ultrafiltration filtration can remove part of PAEs, the Optimum ultrafiltration operation pressure 0.01 MPa. When the influent concentration of PAEs is 10, 15, 20, 25 μg·L-1, the comprehensive removal rate of PAEs from ozone activated carbon process is 55.19%~66.12%, the detection concentration of small molecules DMP and DEP is lower than 3 μg·L-1 , and the treatment effect is better than that of DBP, DEHP. Activated carbon ultrafiltration process has a significant effect on the filtration of high molecular weight PAEs, and the detection concentration of PAEs is 0~3.11 μg·L-1. By a comparison on two kinds of combination process, in low, high influent PAEs concentration, activated carbon—ultrafiltration process on the PAEs removal rate and PAEs end of the effluent concentration are better than that of ozone—activated carbon process treatment. Ultrafiltration, as the third generation water purification process, has a good technological advantage.